面 (miàn): Face; facial expression.
不 (bù): Not; no. A simple negation.
改 (gǎi): To change; to alter.
色 (sè): Color. In this context, it specifically refers to the “color” of one's face or their facial expression (e.g., turning pale with fear or red with anger).
These characters combine literally and powerfully: 面 (face) 不 (not) 改 (change) 色 (color/expression). The meaning is crystal clear—one's expression remains completely unchanged, betraying no inner turmoil.